Analysis of the results gives values for the equilibrium constant for isopropyl nitrite hydrolysis and for the rate constants for nitrous acid nitrosation of the substrate, which are in good agreement with the literature values obtained by direct measurement. For tertiary butyl nitrite the extent of hydrolysis is so large and rapid that the kinetics are identical to those obtained using nitrous acid. The reactions of isopropyl nitrite in isopropanol and tertiary butyl nitrite in tertiary butanol with thiourea and thioglycolic acid have been studied.
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